You did a fantastic job and effort by adding the background in. The stone colors with the sky make this picture appealing to look at. When I first saw this I thought it was Beauty and the Beast because Padme looks a lot like Bella, but I think it works. She also looks very pretty. Anakin's head is a little off. You have it going diagonally upward a bit so I think if you shaved it down it should work. If his head looks to small after that I would increase the size of his whole head just slightly until it matches Padme’s size. However it's by far a very good looking Anakin.
Overall I love it!
Aww thank you!!
Ani's head was the hardest part, I might fix it once it's actually daytime. Thank you for the very useful input! I appreciate it!!
Your welcome! I just wanted to add (because I missed this part) if you want to improve backgrounds, shading where the light hits would help a lot. By default I usually have my sun in the upper right hand corner so every object has shading with a light stroke on the right and a dark stroke on the left. That might work for the pot objects on the balcony.